Glaze Materials
Some glaze materials may cause more pitting than others. An example of this is the mineral rutile. Rutile is added to glazes to give them interesting and varied colours.
A glaze containing rutile can contain beautiful looking crystal patterns, streaks and flecks. However, it can also increase the likelihood of pitting. Other glaze materials that can increase pitting are zinc, strontium carbonate and some glaze binders.
Solution:
If you are making your own glaze, you can see if there is a difference by changing the ingredients. However, if you are buying ready-mixed glazes, you may want to consider using an alternative option.
Glaze Viscosity and Surface Tension
Some glazes are more viscous than others. A viscous glaze is a glaze that is not very flowing or fluid, even when melted during the firing programme.
Because a viscous glaze does not flow or move much, the glaze will have a more difficult time sealing pits that may form during firing. High alumina content or the presence of materials such as zirconia can make the glaze more solid.
Another issue is glaze surface tension. Some glazes have a higher surface tension in the molten state. This can make it difficult for bubbles to break through the glaze surface. Bubbles may not be able to penetrate the glaze or they may break the surface, but there is not enough time for the pits left behind to fuse in the development glaze.
Solution:
Viscosity and surface tension do not depend on each other. Thick glazes do not necessarily have a high surface tension and vice versa.
However, it is possible to reduce viscosity and surface tension by adjusting the glaze in several ways:
Reduce the amount of alumina silicate in the glaze. Clay is a form of alumina silicate. It is added to the glaze to harden it to prevent the biscuit from slipping. But the glaze with higher clay content will be more solid and viscous.
By adding more fluids to the glaze, the glaze will prolong the time the glaze remains molten during glaze firing. This gives it more time to repair pits formed on the surface by the expulsion of gases.
Glaze Consistency
If your glaze is too thick or viscous, you may not get a good application on the biscuit. A glaze that is too thick is less likely to form a well adhered, even layer on the biscuit.
If the glaze is too thick in application, the glaze is more likely to flake off the biscuit before or during baking. Also, as mentioned above, an excessively thick layer of glaze is more likely to encounter pitting problems.
Solutions:
Add a small amount of deflocculant, such as glaze sodium silicate. This will thin the glaze without diluting it with water and make it less viscous. A deflocculated glaze will adhere more successfully to the biscuit and will be less likely to form pits.